Hello....When using Dreamweaver and WebAssist products they rely on PHP/MySQL
PHP - is the programming language
MySQL is the database system
You need to scrap Microsoft Access as thats for ASP programming language etc.
You need to first create a working environment for your project using dreamweaver and what is know as a WAMP stack (if Windows) or MAMP Stack (if Apple Mac)
They are easy to setup, just a little program you can get from the internet for free.
WAMPServer is the most popular
and XXAMP is also popular
en/
xampp.html
Then what you would do is create what is known as a LOCAL HOST using one of the above.
Then in Dreamweaver you would set up a local site
Then you would need to login to PHPMyAdmin (which is the MySQL databased installed by one of the 2 programs above) then create your database in the PHPMyAdmin environment.
Thats the summary - if you want more details then feel free to ask :)
Chris