Just want to be sure which config forler you are talking about. Are you saying to change
C:\Users\***\AppData\Roaming\Adobe\Dreamweaver CS6\en_US\Configuration ?
Or is it another one?
BTW - I did get the following error (attached pic) )a couple times as well in the beginning. I uninstalled all the apps this morning and tried again only to have it come up again. Only app installed at this time is Data Bridge. Hope this helps.