It appears the default toolbar doesn't include all of the available options. You could edit it with the new html editor, or you could do a simple update in the associated pages.
You'll find a line that refers to:
$CKEditor_config["toolbar"]
You can add or remove toolbar options manually from the array built on that line.
All of the options appear here:
$CKEditor_config["toolbar"] = array(
array( 'Source','-','Save','NewPage','Preview','-','Templates'),
array( 'Cut','Copy','Paste','PasteText','PasteFromWord','-','Print','SpellChecker','Scayt'),
array( 'Undo','Redo','-','Find','Replace','-','SelectAll','RemoveFormat'),
array( 'Form','Checkbox','Radio','TextField','Textarea','Select','Button','ImageButton','HiddenField'),
array( 'BidiLtr','BidiRtl'),
('/'),
array( 'Bold','Italic','Underline','Strike','-','Subscript','Superscript'),
array( 'NumberedList','BulletedList','-','Outdent','Indent','Blockquote','CreateDiv'),
array( 'JustifyLeft','JustifyCenter','JustifyRight','JustifyBlock'),
array( 'Link','Unlink','Anchor'),
array( 'Image','Flash','Table','HorizontalRule','Smiley','SpecialChar','PageBreak'),
('/'),
array( 'Styles','Format','Font','FontSize'),
array( 'TextColor','BGColor'),
array( 'Maximize','ShowBlocks','-','About'));
It looks like we didn't properly update all of the toolbar options since some of the names have been changed... it is supposed to have those listed... we'll get that updated... the default should probably be:
$CKEditor_config["toolbar"] = array(
array( 'Source','DocProps','-','Preview'),
array( 'Cut','Copy','Paste','PasteText','PasteFromWord','-','SpellChecker'),
array( 'Undo','Redo','-','Find','Replace','-','SelectAll','RemoveFormat'),
array( 'Image','Flash','Table','HorizontalRule','Smiley', 'SpecialChar','PageBreak'),
('/'),
array( 'Bold','Italic','Underline','Strike','-','Subscript','Superscript'),
array( 'NumberedList','BulletedList','-','Outdent','Indent','Blockquote','CreateDiv'),
array( 'JustifyLeft','JustifyCenter','JustifyRight','JustifyBlock'),
array( 'Link','Unlink','Anchor'),
('/'),
array( 'Format','Font','FontSize'),
array( 'TextColor','BGColor'),
array( 'Maximize','ShowBlocks'));