======================Code-====================
$from = “From: webmaster@sk8photos.com <webmaster@sk8photos.com>\r\n”;
=====================end Code============================
Just while you're waiting for a real expert on PHP to get back to you (at PHP coding I'm a novice) the error code is saying that it doesn't like the colon in "From:" Try using the ascii code for a colon instead ":" (without the speech marks).
If I had this situation, that's what I would try. Hope it helps.