all of the print settings are specific to the browser, and cannot be controlled by the material being printed.
as for entering the to and from address, create a form on your page, add text fields for the to address and the from address.
In UE click the lightning bolt next to the to address and select the to form element
For the from address, most servers require that the from address be a valid email address for your domain, click the from button and in the advanced from settings you can bind the Reply to Address to the from form element.