you will need to update the WA_eCart/WA_eCart_Definition_PHP.php file, and change:
$header = "POST /cgi-bin/webscr HTTP/1.0\r\n";
$header .= "Content-Type: application/x-www-form-urlencoded\r\n";
to:
$header = "POST /cgi-bin/webscr HTTP/1.1\r\n";
$header .= "Content-Type: application/x-www-form-urlencoded\r\n";
$header .= "Host: www.paypal.com\r\n";