Currently there is no sorting on the option values. but to be consistent we can add a sorting to the query_OptionValues query. In your Product_Details.php, look for the query_OptionValues query and add:
ORDER BY ps3_options.OptionID
to the end of the query. You will need to do this in three places on the Product_Details.php. This will order the values by the order you entered them into the database.
let me know if you have any questions.