Ahhh OK all I had to do was...
1) Add a field to the database table ps3_orderdetails called DetailOptions
2) Edit the Store Details in Database behavior on confirm.php to bind the eCart Column "Options" to ps3_orderdetails.DetailOptions
3) Edit Admin > orders_Detail.php and make it display the DetailOptions
Kinda seems like this'd be an out of the box capability. I mean, so we can see what options a customer selected? Or perhaps I am going at this all wrong.
Easy fix though, thanks Eric!