The answer is to replace the library file found in these locations (Mac only perhaps someone could provide the equivalent windows location) with the new one Ray attached to this thread.
/Users/USERNAME/Library/Application Support/Adobe/Dreamweaver CS4/en_US/Configuration/shared/WebAssist/ApplicationBuilder/Helpers/library.php
/Users/USERNAME/Library/Application Support/Adobe/Dreamweaver CS5/en_US/Configuration/Shared/WebAssist/ApplicationBuilder/Helpers/library.php
This will ensure when you reopen the wizard the correct library file is written to WA_DataAssist/library.php
Hope that helps
Question: because DW needs to redo Config so much, will this need to keep being replaced each time, or will it travel over? Thanks