You should be able to make use of the regular eCommerce db, but you will also need to customize it a bit. It seems that you will need to ensure that you have all of the various options recorded in tables including the option values and the price for that option.
This is a going to be custom and you will need to determine how your data should relate. The problem is that the table you posted is just tabular data, you will need to ensure that you have all of this information in tables that relate to the items. If you have not seen it already you should take a look at our Database Starter Kit for php, it is a great educational resource on database design and manipulation. Here is a link: