Under Settings -> Emails -> Order receipts, add your email address in the CC or BCC sections to have a copy of the order receipts sent to you when an order is placed.
Your friends over here at WebAssist! These Dreamweaver extensions will assist you in building unlimited, custom websites.
These out-of-the-box solutions provide you proven, tested applications that can be up and running now. Build a store, a gallery, or a web-based email solution.