i must be missing something.
The shipping looks to be calculating correctly to me based on the settings in your cart object.
i only see one shipping rule, that is set to charge 9.00 if the Country is AU and the State province is not ACT or QBN.
If i select NSW/Queanbeyan or Australian Capital Territory as the State, no shipping is applied,
if i select any other state, 9.00 is applied.
that is the way the rule is configured to work.
as for the discount, you can add a 10% discount on the discount tab.
Set the trigger to Number of unique items > 0
and the calculation to:
Based on cart subtotal "Times" "0.10"